Sodium N-bromo-2-chlorobenzenesulfonamidate sesquihydrate
نویسندگان
چکیده
In the title compound, Na(+)·C(6)H(4)BrClNO(2)S(-)·1.5H(2)O, one water mol-ecule has crystallographically imposed twofold symmetry. The Na(+) cation shows a pseudo-octa-hedral coordination provided by three O atoms of water mol-ecules and three sulfonyl O atoms of different N-bromo-2-chloro-benzene-sulfonamidate anions. The S-N distance of 1.579 (6) Å is consistent with an S=N double-bond character. The crystal structure is stabilized by O-H⋯Br, O-H⋯N and O-H⋯O hydrogen bonds.
منابع مشابه
Potassium N-bromo-2-chlorobenzenesulfonamidate sesquihydrate
In the structure of the title compound, K(+)·C(6)H(4)BrClNO(2)S(-)·1.5H(2)O, the K(+) ion is hepta-coordinated by three O atoms from water mol-ecules and by four sulfonyl O atoms of N-bromo-2-chloro-benzene-sulfonamidate anions. The S-N distance of 1.582 (4) Å is consistent with an S=N double bond. The crystal structure is stabilized by inter-molecular O-H⋯Br and O-H⋯N hydrogen bonds. The asymm...
متن کاملPotassium N-bromo-2,4-dichlorobenzenesulfonamidate sesquihydrate
The asymmetric unit of the title salt, K(+)·C(6)H(3)BrCl(2)NO(2)S(-)·1.5H(2)O, contains one K(+) cation, one N-bromo-2,4-dichlorobenzenesulfonamidate anion, one water molecule in general position and one water molecule located on a twofold rotation axis. The K(+) cation is hepta-coordinated by three water O atoms and four sulfonyl O atoms from three symmetry-related N-bromo-2,4-dichloro-benzene...
متن کاملPotassium N-bromo-2-methylbenzenesulfonamidate sesquihydrate
In the structure of the title compound, K(+)·C(7)H(7)BrNO(2)S(-)·1.5H(2)O, the K(+) ion is hepta-coordinated by three O atoms from water mol-ecules and by four sulfonyl O atoms of N-bromo-2-methyl-benzene-sulfonamide anions. The S-N distance of 1.577 (5) Å is consistent with an S=N double bond. The crystal structure comprises sheets in the ac plane which are further stabilized by O-H⋯Br and O-H...
متن کاملPotassium N-bromo-4-chlorobenzenesulfonamidate monohydrate
In the structure of the title compound, K(+)·C(6)H(4)BrClNO(2)S(-)·H(2)O, the K(+) cation is hepta-coordinated. It is connected to two water O atoms, four sulfonyl O atoms and one Br atom. Further, the sulfonyl and water O atoms in the structure are bridged in a bidentate fashion. The S-N distance of 1.584 (6) Å is consistent with an S-N double bond, The crystal structure is stabilized by inter...
متن کاملPantoprazole Sodium Sesquihydrate Complexes: Synthesis, Characterization, Potentiometric Determination and DNA interaction
The synthesis and characterization of solid complexes for pantoprazole sodium sesquihydrate (PNZ) with Cd(II), Hg(II) and Zn(II) metals in molar ratios M:L = 1:2 was studied. The complexes are stable in the solid state and are soluble only in DMF and DMSO. The metal complexes were characterized by elemental analysis, molar conductivity measurements, magnetic susceptibility, UV spectrophotometry...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011